Choudhury, Amitava ; Natarajan, Srinivasan ; Rao, C. N. R. (2001) A layered zinc phosphate,[C6N4H22][Zn6(PO4)4(HPO4)2],formed by one-dimensional tubes Journal of Solid State Chemistry, 157 (1). pp. 110-116. ISSN 0022-4596
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00224...
Related URL: http://dx.doi.org/10.1006/jssc.2000.9046
Abstract
An open-framework zinc phosphate, [C6N4H22] [Zn6(PO4)4(HPO4)2] (I), with alternating inorganic and organic layers has been synthesized hydrothermally from a starting mixture of ZnO, HCl, H3PO4, H2C2O4, and triethylenetetramine. Single-crystal data for I: monoclinic, space GROUP =P21/c (No. 14), a=9.881(1), b=16.857(1), c=8.286(1) Å, β=96.7(1)°, V=1370.8(1) Å3, Z=2, R1=0.06, and wR2=0.13 [1408 observed reflections with I>2σ(I)]. The structure of I comprises a network of ZnO4, PO4, and PO3(OH) tetrahedra forming one-dimensional tubes. The tubes, in turn, are linked via oxygen atoms forming macroanionic inorganic layers with eight-membered apertures. The one-dimensional tube-like architecture in I is a novel feature worthy of note.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 27792 |
| Deposited On: | 11 Dec 2010 07:54 |
| Last Modified: | 10 Jun 2011 09:11 |
Repository Staff Only: item control page
