Thirumurugan, A. ; Pati, Swapan K. ; Green, Mark A. ; Natarajan, Srinivasan (2004) A gadolinium diphenate coordination polymer,∞1[Gd2(H2O)2(C14H8O4)3], with one-dimensional structure Zeitschrift fur Anorganische und Allgemeine Chemie, 630 (4). pp. 579-584. ISSN 0044-2313
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.20...
Related URL: http://dx.doi.org/10.1002/zaac.200300374
Abstract
A hydrothermal reaction of Gd(NO3)3 and 2, 2'-diphenic acid give rise to a new coordination compound 1∞[Gd2(H2O)2(C14H8O4)3] with one-dimensional structure. Single crystal X-ray studies shows that the compound has infinite O-Gd-O one-dimensional chains resulting from a bonding between Gd3+ cations and diphenate anions. The Gd3+ ions are distorted dodecahedra with respect to oxygen atoms. Magnetic investigations show no ordering up to 4K and the compound exhibit photoluminescence at room temperature.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Hydrothermal Synthesis; Diphenic Acid; Gadolinium |
| ID Code: | 27791 |
| Deposited On: | 11 Dec 2010 07:54 |
| Last Modified: | 10 Jun 2011 08:27 |
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