A new open-framework zinc arsenate [C4N3H16]2[Zn5(AsO4)4(HAsO4)2]

Koteswara Rao, V. ; Natarajan, Srinivasan (2010) A new open-framework zinc arsenate [C4N3H16]2[Zn5(AsO4)4(HAsO4)2] Inorganic Chemistry Communications, 13 (1). pp. 163-166. ISSN 1387-7003

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13877...

Abstract

A three-dimensional zinc arsenate with an interrupted zeolitic framework (-IIO), [C4N3H16]2[Zn5(AsO4) 4(HAsO4)2], I has been synthesized solvothermally. The structure is built up from ZnO4, AsO4 and HAsO4 tetrahedral units connected alternatively through their vertices forming the 3-D structure possessing one-dimensional channels bound by 10 T-atoms (T = Zn, As). The framework density of the structure is 10.4 T-atoms which indicates considerable openness in its structure.

Item Type:Article
ID Code:27769
Deposited On:11 Dec 2010 07:56
Last Modified:04 Mar 2011 05:58

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