Vaidhyanathan, Ramanathan ; Natarajan, Srinivasan ; Rao, C. N. R. (2003) Aliphatic dicarboxylates with three-dimensional metal-organic frameworks possessing hydrophobic channels Dalton Transactions, 8 . pp. 1459-1464. ISSN 1477-9226
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Related URL: http://dx.doi.org/10.1039/ b212314m
Abstract
Two three-dimensional open-framework metal dicarboxylates possessing channels with a hydrophobic environment have been synthesized. One is a malonate of the formula, [Cd(O2C-CH2-CO2)(H2O)]·H2O, I, and the other a glutarate of the formula [Mn(O2C-(CH2)3-CO2)], II. The three-dimensional structure of I is attained through infinite Cd-O-Cd corner-linkages. On the other hand, II, contains Mn-O-Mn layers cross-linked by MnO6 octahedra and glutarate moieties.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 27761 |
| Deposited On: | 11 Dec 2010 07:57 |
| Last Modified: | 17 May 2016 10:58 |
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