Vaidhyanathan, R. ; Natarajan, Srinivasan ; Rao, C. N. R. (2003) Solvothermal synthesis of a layered open-framework chlorocadmium oxalate,Cd2(C2O4)0.5Cl3NaCl.4 H2O European Journal of Inorganic Chemistry, 2003 (9). pp. 1675-1680. ISSN 1434-1948
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejic.20...
Related URL: http://dx.doi.org/10.1002/ejic.200200612
Abstract
The metathesis reaction between CdCl2·2H2O and sodium oxalate in n-hexanol under solvothermal conditions yields a hybrid compound of formula Cd2(C2O4)0.5Cl3NaCl·4H2 O. It consists of one-dimensional chains formed by Cd and Cl atoms, containing μ2(Cl) and μ3(Cl) bridges, and cross-linked by oxalate units to give a layered structure. The Na+ ions and water molecules occupy the interlamellar spaces.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Materials Science; Cadmium; Solvothermal Synthesis; Metathesis |
| ID Code: | 27759 |
| Deposited On: | 11 Dec 2010 07:57 |
| Last Modified: | 10 Jun 2011 08:35 |
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