Natarajan, Srinivasan (2003) Hydrothermal synthesis and crystal structure of a two-dimensional zinc vanadate,[(NH3(CH2)3NH)Zn]23+ [V4O13]6- Inorganica Chimica Acta, 348 . pp. 233-236. ISSN 0020-1693
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00201...
Related URL: http://dx.doi.org/10.1016/S0020-1693(03)00039-2
Abstract
The hydrothermal reaction of ZnCl2, V2O5, 1,3-diaminopropane in water at 155°C for 120 h produces [(NH3(CH2)3NH)Zn]23+ [V4O13]6-, I. The connectivity between ZnO3N and VO4 tetrahedral units gives rise to a unique layered architecture, with the amine molecule directly bonded to the Zn center pointing in a direction perpendicular to the plane of the layers. The presence of V4O13 linear chains in I is noteworthy.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Zinc; Vanadium; Hydrothermal; Hybrid; Diaminopropane |
| ID Code: | 27747 |
| Deposited On: | 11 Dec 2010 07:59 |
| Last Modified: | 11 Dec 2010 07:59 |
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