Vaidhyanathan, R. ; Natarajan, Srinivasan ; Rao, C. N . R. (2002) A layered zinc oxalate possessing a 12-membered honeycomb aperture, stabilized by an amine and an alkali cation Solid State Sciences, 4 (5). pp. 633-639. ISSN 1293-2558
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S12932...
Related URL: http://dx.doi.org/10.1016/S1293-2558(02)01307-9
Abstract
A new layered anionic zinc oxalate of the formula, K[C6N2H13][Zn2(C2O4)3].4H2O containing 12-membered honeycomb apertures has been synthesized hydrothermally in the presence of DABCO and K+. A noteworthy feature of the structure is the presence of 12-membered apertures, aligned in such a way as to create pseudo one-dimensional tunnels as in zeolitic structures. The amine, K+ and water molecules are present in the tunnels.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Crystal Growth; Framework; Host-guest Chemistry; Organic-inorganic Hybrid; Zinc |
| ID Code: | 27745 |
| Deposited On: | 11 Dec 2010 07:59 |
| Last Modified: | 10 Jun 2011 08:53 |
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