Chidambaram, D. ; Natarajan, S. (1998) Synthesis and structure of a new open-framework zinc phosphate:[Zn3(PO4)2(HPO4)0.5]-0.5 [(NH3(CH2)2(NH3)]2+H2O Materials Research Bulletin, 33 (8). pp. 1275-1281. ISSN 0025-5408
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00255...
Related URL: http://dx.doi.org/10.1016/S0025-5408(98)00100-7
Abstract
A new open-framework zinc phosphate, [Zn3(PO4)2(HPO4)0.5]- [0.5(NH3(CH2)2(NH3)]2+H2O, having Zn-O-Zn linkages was synthesized by hydrothermal technique. The structure consists of a network of ZnO4 and PO4 tetrahedra in which the vertices are shared. Water molecules are present in a 6-membered channel and the protonated ethylenediamine molecule is in the middle of a 8-membered channel, creating alternating hydrophobic and hydrophilic channels.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | A. Inorganic Compounds; A. Microporous Materials; B. Chemical Synthesis; C. X-ray Diffraction; D. Crystal Structure |
| ID Code: | 27702 |
| Deposited On: | 11 Dec 2010 08:25 |
| Last Modified: | 10 Jun 2011 09:53 |
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