Addition of amines and halogens to fullerenes C60 and C70

Seshadri, Ram ; Govindaraj, A. ; Nagarajan, R. ; Pradeep, T. ; Rao, C. N. R. (1992) Addition of amines and halogens to fullerenes C60 and C70 Tetrahedron Letters, 33 (15). pp. 2069-2070. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...

Related URL: http://dx.doi.org/10.1016/0040-4039(92)88144-T

Abstract

In solution phase, aliphatic amines add on to fullerenes; vapourization of graphite in presence of methylamine gives nitrogeneous C60 derivatives. Reactions of C60 with SbCl5 and liquid Br2 yield halogen adducts.

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