Etters, R. D. ; Flurchick, K. ; Pan, R. P. ; Chandrasekharan, V. (1981) Thermodynamic properties and phase transitions in CO2 molecular clusters Journal of Chemical Physics, 75 (2). pp. 929-936. ISSN 0021-9606
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Official URL: http://link.aip.org/link/jcpsa6/v75/i2/p929/s1
Related URL: http://dx.doi.org/10.1063/1.442091
Abstract
The thermodynamic properties of (CO2)N molecular aggregates of size 2 N 13 have been investigated. These crystallites exhibit well defined orientational order-disorder rotational transitions accompanied by a structural transition into a plastic crystallite phase. In addition, they exhibit melting and disassociation transitions. It is shown that the interpretation of experimental data, based upon dimer properties, depends crucially on these results. Equilibrium structures and orientations are also given.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Physics. |
| Keywords: | Carbon Dioxide; Thermodynamic Properties; Agglomeration; Condensates; Phase Transformations; Nucleation |
| ID Code: | 27372 |
| Deposited On: | 10 Dec 2010 12:40 |
| Last Modified: | 27 May 2011 09:59 |
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