Alikhani, M. E. ; Silvi, B. ; Perchard, J. P. ; Chandrasekharan, V. (1989) Reinvestigation of the Raman spectra of dihydrogen trapped in rare gas solids. I. H2, HD, and D2 monomeric species Journal of Chemical Physics, 90 (10). pp. 5221-5231. ISSN 0021-9606
Full text not available from this repository.
Official URL: http://jcp.aip.org/resource/1/jcpsa6/v90/i10/p5221...
Related URL: http://dx.doi.org/10.1063/1.456475
Abstract
The vibration-rotation and pure rotational Raman spectra of H2, HD, and D2 trapped in Ar, Kr, and Xe matrices have been recorded at 9 K. The frequencies which have been measured within an accuracy of 0.3 cm-1 are compared to the results of recent calculations. Except for the S0(0) line of HD the agreement between observed and calculated matrix shifts is satisfactory. The anomalous blue shift observed for the S0(0) line of HD is well interpreted within the rotation translation coupling (RTC) framework.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Physics. |
| Keywords: | Hydrogen; Hydrogen Deuteride; Deuterium; Raman Spectra; Matrix Isolation; Ultralow Temperature; Argon; Krypton; Xenon; Matrix Materials; Spectral Shift |
| ID Code: | 27349 |
| Deposited On: | 10 Dec 2010 12:42 |
| Last Modified: | 27 May 2011 09:51 |
Repository Staff Only: item control page
