Nasipuri, Dhanonjoy ; Das, Gautam (1979) Cyclisation reactions. Part 5. Synthesis of pallescensin A, a furanoid sesquiterpene by cationic cyclisation of an ω-furyldiolefin and of the corresponding epoxy-olefin Journal of the Chemical Society, Perkin Transactions 1 . pp. 2776-2778. ISSN 0300-922X
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Official URL: http://www.rsc.org/publishing/journals/article.asp...
Related URL: http://dx.doi.org/10.1039/P19790002776
Abstract
A biomimetic synthesis of pallescensin A (1), a furanoid sesquiterpene of natural origin is effected by concerted cyclisation of (6E)-9-(3-furyl)-2,6-dimethylnona-2,6-diene (2). The diene (2) has also been converted into a mono-epoxide (3) and the latter cyclised stereoselectively into 3-β-hydroxypallescensin A(4) which is subsequently deoxygenated to (±)-pallescensin A.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 27188 |
| Deposited On: | 10 Dec 2010 12:59 |
| Last Modified: | 10 Dec 2010 12:59 |
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