Nasipuri, Dhanonjoy ; Das, Gautam ; Dalal, Ila De (1977) Autoxidation of 3,4-dihydro-1-methylnaphthalen-2(1H)-one Journal of the Chemical Society. Perkin transactions 1 (23). pp. 2558-2559. ISSN 0300-922X
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Official URL: http://www.rsc.org/publishing/journals/article.asp...
Related URL: http://dx.doi.org/10.1039/P19770002558
Abstract
3,4-Dihydro-1-methylnaphthalen-2(1H)-one (1) is found to undergo autoxidation giving at least three distinct crystalline products, namely. 3-(2-acetylphenyl)propionic acid (5), 1,1-bi-[3,4-dihydro-1-methylnaphthalen-2(1H)-one](7), and 3,4-dihydro-1-hydroxy-1-methylnaphthalen-2(1H)-one (6). A new synthesis of the ketone (1) is described using a modified Curtius reaction with 3,4-dihydro-1-methyl-2-naphthoic acid (8) which excludes the use of any oxidising agent.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 27107 |
| Deposited On: | 08 Dec 2010 12:42 |
| Last Modified: | 04 Mar 2011 04:51 |
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