Thirumalai Perumal, P. ; Vivekananda Bhatt, M. (1989) Quinone studies. Part III. Metal ion-catalysed oxidation of halophenols and halonaphthols by peroxidisulphate Proceedings of the Indian Academy of Sciences - Chemical Sciences, 101 (1). pp. 25-32. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/101/2/25-32...
Related URL: http://dx.doi.org/10.1007/BF02869382
Abstract
Oxidation of representative halophenols and halonaphthols by peroxidisulphate has been examined. The influence of metallic ions, viz. Cu2+, Fe3+, Ag+, on the above reaction has been studied. Cu2+ ion-catalyzed oxidation gives halo-1, 4-quinones in excellent yield. Potassium bis(biureto)cuprate(III) complex also oxidises halophenols to halo-1, 4-quinones.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Metal Ion-catalysed Oxidation; Halophenols; Halonaphthols; Peroxidisulphate; Halo-1; 4-quinones |
| ID Code: | 2673 |
| Deposited On: | 08 Oct 2010 08:39 |
| Last Modified: | 16 May 2016 13:37 |
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