Synthesis of the lactone of 2-carboxy-4-hydroxy-7-methoxy-1, 2, 3, 4-tetrahydrophenanthrone

Banerjee, D. K. ; Bagavant, G. (1961) Synthesis of the lactone of 2-carboxy-4-hydroxy-7-methoxy-1, 2, 3, 4-tetrahydrophenanthrone Proceedings of the Indian Academy of Sciences, Section A, 53 (2). pp. 113-122. ISSN 0370-0089

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Official URL: http://www.ias.ac.in/j_archive/proca/53/2/113-122/...

Related URL: http://dx.doi.org/10.1007/BF03045798

Abstract

Starting from 6-methoxynaphthaldehyde-2, 2-carboxy-7-methoxy-1, 2, 3, 4-tetrahydrophenanthrone-4 was prepared. Sodium borohydride reduction of the keto-acid followed by chromic acid oxidation yielded the lactone of 2-carboxy-4-hydroxy-7-methoxy-1, 2, 3, 4-tetrahydrophenanthrone. Alkylation of the lactone of 2-carboxy-4-hydroxy-6-methoxytetralone was not promising.

Item Type:Article
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ID Code:26379
Deposited On:06 Dec 2010 12:38
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