Nayak, A. K. ; Sarkar, S. K. ; Mittal, J. P. (1993) Product distributions in UV and IR laser chemistry of CnF2n+1I(n = 1, 2) in the presence of H2 Journal of Photochemistry and Photobiology A: Chemistry, 71 (1). pp. 1-7. ISSN 1010-6030
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/101060...
Related URL: http://dx.doi.org/10.1016/1010-6030(93)87001-4
Abstract
The UV and IR photolysis of trifluoroiodomethane and pentafluoroiodoethane in the presence of hydrogen were studied. The products were quantitatively analysed by IR spectrophotometry and temperature-programmed gas chromatography. The photolysis product distribution using different experimental parameters was obtained. The difference between the product distributions in IR multiphoton dissociation (IRMPD) and conventional UV photolysis has been explained in terms of the various competing rate constants and the concentration of the perfluoroalkyl radicals generated in the irradiated volume.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25813 |
| Deposited On: | 04 Dec 2010 11:35 |
| Last Modified: | 08 Jun 2011 04:51 |
Repository Staff Only: item control page
