Shou-te, Lian C.T. ; Mittal, Jai P. (1984) Matrix isolation studies of the transients produced in the gamma radiolysis of decafluorobenzophenone and triethylamine: radiolytically generated contact ammonium ion-pair of decafluorobenzophenone Radiation Physics and Chemistry (1977), 24 (5-6). pp. 459-464. ISSN 0146-5724
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/014657...
Related URL: http://dx.doi.org/10.1016/0146-5724(84)90178-X
Abstract
The radiolytically generated radical anion of decafluorobenzophenone normally leads to the formation of ketyl radical by protonation. However, in the presence of triethylamine, the ketyl radical formation can be prevented by a contact ion-pair formation. The absorption spectra for such an ion-pair is located at a shorter wavelength than the corresponding solvated radical anion and exhibits solvent-dependent spectral shift characteristic of the radical anion of decafluorobenzophenone.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25805 |
| Deposited On: | 04 Dec 2010 11:38 |
| Last Modified: | 08 Jun 2011 06:22 |
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