Shou-tea, Lian C. T. ; Mittal, Jai P. (1985) Ionic species produced on gamma radiolysis: studies by matrix isolation technique-I. Electronic absorption spectra of perfluorosubstituted aromatic radical anions Radiation Physics and Chemistry (1977), 26 (6). pp. 739-743. ISSN 0146-5724
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/014657...
Related URL: http://dx.doi.org/10.1016/0146-5724(85)90116-5
Abstract
The absorption spectra of several perfluorosubstituted aromatic radical anions are compared with the corresponding perhydro compounds in which the various transitions involved have been assigned to those predicted theoretically. The electronic absorption spectra were obtained for pentafluorostyrene, pentafluorobenzaldehyde, pentafluorobenzoic acid, pentafluorobenzonitride, tetrafluorophthalic acid and pentafluoroaniline, by gamma radiolysis in 2-methyltetrahydrofuran at 77 K. A general similarity in the absorption spectra between the perfluorinated and the corresponding perhydro radical anion is observed except for a shift in the absorption band.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25739 |
| Deposited On: | 04 Dec 2010 11:47 |
| Last Modified: | 08 Jun 2011 06:21 |
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