Kumar, Awadhesh ; Vatsa, R. K. ; Naik, P. D. ; Rama Rao, K. V. S. ; Mittal, J. P. (1992) Time-resolved infrared fluorescence from an IR multiphoton dissociation product of trifluoroacetic anhydride Chemical Physics Letters, 200 (3). pp. 283-289. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(92)80012-Z
Abstract
Infrared multiphoton dissociation of trifluoroacetic anhydride by a pulse CO2 yields CF3COF, C2F4 and CO2 as the major, and COF2, CO and C2F6 as minor photoproducts. Infrared fluorescence from a photoproduct, COF2, is observed. The intermolecular V → V and V → T relaxation rate constants are calculated to be 8× 104 and 3× 104 s-1 Torr-1, respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25692 |
| Deposited On: | 04 Dec 2010 11:54 |
| Last Modified: | 08 Jun 2011 05:00 |
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