Chowdhury, P. K. ; Pola, J. ; Rama Rao, K. V. S. ; Mittal, J. P. (1987) TEA CO2 laser driven oxidation of tetrafluoroethene and decafluorocyclopentane with molecular oxygen. Evidence for the dioxetane mechanism Chemical Physics Letters, 142 (3-4). pp. 252-254. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(87)80932-6
Abstract
Time-resolved emission spectra of the TEA CO2 laser induced oxidation of tetrafiuoroethene and decafluorocyclopentane with molecular oxygen indicate that the oxidation of tetrafluoroethene occurs by at least two processes. The dioxetane mechanism represents a faster reaction compared to the oxidation of transiently formed difluorocarbene.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 25665 |
| Deposited On: | 04 Dec 2010 11:58 |
| Last Modified: | 08 Jun 2011 06:13 |
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