Interaction of the excited singlet state of disubstituted anthraquinones with aromatic hydrocarbons: a fluorescence-quenching study

Pal, Haridas ; Palit, Dipak K. ; Mukherjee, Tulsi ; Mittal, Jai P. (1990) Interaction of the excited singlet state of disubstituted anthraquinones with aromatic hydrocarbons: a fluorescence-quenching study Chemical Physics Letters, 173 (4). pp. 354-359. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(90)85283-I

Abstract

The dynamic nature of the quenching of the fluorescence of 1,4-amino- and hydroxy-substituted 9,10-anthraquinone, with benzene, alkylbenzenes and other aryl hydrocarbons as quenchers, indicates formation of exciplexes, where charge transfer (CT) occurs from the S0 (quencher) to the S1 (fluorophore), as kq decreases with increasing ionisation potential of the quenchers, Exciplex emission spectra and kinetics have been established.

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Deposited On:04 Dec 2010 11:59
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