Palit, Dipak K. ; Mohan, Hari ; Mittal, Jai P. (1998) Photophysical properties of C60H18 and C60H36: a laser flash photolysis and pulse radiolysis study Journal of Physical Chemistry A, 102 (24). pp. 4456-4461. ISSN 1089-5639
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp980190o
Related URL: http://dx.doi.org/10.1021/jp980190o
Abstract
Spectroscopic and photophysical properties of two hydrogenated fullerenes, namely, C60H18 and C60H36, have been studied in benzene solution using laser flash photolysis and pulse radiolysis techniques. Samples of C60H18 and C60H36 used were prepared by the reduction of C60 with Zn/concentrated HCl in benzene or toluene at normal (for C60H36) or at high (for C60H18) temperature and pressure. It is reported that C60H18 and C60H36 prepared by these methods have tetrahedral (T) symmetry containing four highly delocalized benzenoid rings, and a crown structure with C3v symmetry, respectively. Owing to hydrogenation, the fluorescence band of C60 shifts toward the blue and both the fluorescence quantum yields and the singlet-state (S1) lifetimes of the more hydrogenated species increase compared with those of the parent fullerene molecule. Triplet quantum yields reduce considerably (e.g., φ T for C60H18 and C60H36 is 0.15 and 0.1, respectively) compared with unity for C60. Also the singlet-singlet and triplet-triplet absorption spectra show considerable differences from those of C60. Owing to successive hydrogenation of C60, the intensity of the near-IR band (at ca. 880 nm) in the singlet-singlet absorption spectra decreases and that in the visible (at ca. 500 nm) becomes more prominent. In the triplet-triplet absorption spectrum, the major band, which is seen at 740 nm for C60, gradually shifts to the blue in the more hydrogenated species. The spectroscopic properties of the hydrogenated fullerenes used by us have been seen to be different in many aspects compared with those reported by Bensasson et al. (Chem. Phys. 1997, 215, 111), possibly owing to the different symmetries of these derivatives prepared by different hydrogenation methods.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 25609 |
Deposited On: | 04 Dec 2010 12:04 |
Last Modified: | 12 Jul 2012 04:31 |
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