Gas-phase halo alkylation of C60-fullerene by ion-molecule reaction under chemical ionization

Srinivas, R. ; Vairamani, M. ; Mathews, C. K. (1993) Gas-phase halo alkylation of C60-fullerene by ion-molecule reaction under chemical ionization Journal of the American Society for Mass Spectrometry, 4 (11). pp. 894-897. ISSN 1044-0305

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/104403...

Related URL: http://dx.doi.org/10.1016/1044-0305(93)87007-Y

Abstract

Chemical ionization (CI) mass spectra of C60-fullerene were studied using 1,2-dibromoethane and 1,2-dichloroethane as CI reagents. The ion-molecule reaction between C60 and C2H4X+ (X = Br and Cl) leads to the formation of (C60 + C2H4X)+adducts. The collision-induced dissociation of the adducts reveal gas phase halo alkylation of C60-fullerene involving the C---C bond formation.

Item Type:Article
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ID Code:25408
Deposited On:06 Dec 2010 13:26
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