Thermodynamic functions of alkaline earth monouranates from calorimetric measurements

Saha, Rita ; Babu, R. ; Nagarajan, K. ; Mathews, C. K. (1988) Thermodynamic functions of alkaline earth monouranates from calorimetric measurements Thermochimica Acta, 131 . pp. 183-189. ISSN 0040-6031

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004060...

Related URL: http://dx.doi.org/10.1016/0040-6031(88)80072-8

Abstract

High temperature differential calorimetry was used to determine the enthalpy increments of BaUO4, α-SrUO4 and CaUO4 relative to room temperature. The measurements covered the temperature range 1000-1735 K. From these enthalpy values other thermodynamic functions, such as CXXXpT, SXXXT and -(GXXXT - HXXX298)/T, were deduced using CXXXp298 and SXXX298 from the literature. The high temperature CXXXpT values for the monouranates obtained in this study are discussed in relation to the low temperature data available in the literature.

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