Inorganic quadricyclanes: synthesis and characterization of novel sulfur- and selenium-bridged mixed Cr/Fe clusters, CrFe2(CO)10E4 (E = S, Se). Crystal structure of CrFe2(CO)10Se4

Mathur, Pradeep ; Sekar, P. ; Rheingold, Arnold L. ; Liable-Sands, Louise M. (1997) Inorganic quadricyclanes: synthesis and characterization of novel sulfur- and selenium-bridged mixed Cr/Fe clusters, CrFe2(CO)10E4 (E = S, Se). Crystal structure of CrFe2(CO)10Se4 Organometallics, 16 (1). pp. 142-144. ISSN 0276-7333

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Official URL: http://pubs.acs.org/doi/abs/10.1021/om9606754

Related URL: http://dx.doi.org/10.1021/om9606754

Abstract

The new clusters CrFe2(CO)10E4 (E = S, 1; E = Se, 2) have been isolated from the room-temperature reactions of Fe2(CO)6( μ-E2) and Cr(CO)5(THF), and the structure of CrFe2(CO)10Se4has been established by single-crystal X-ray diffraction methods.

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