Mathur, Pradeep ; Chakrabarty, Debojit ; Munkir Hossain, Md. (1991) Mixed chalcogen carbonyl compounds: synthesis and characterisation of (CO)6Fe2(μ3-Se)(μ3-Te)Pt(PPh3)2 Fe3(CO)7(PPh3)2(μ3-Se)(μ3-Te) Journal of Organometallic Chemistry, 401 (1-2). pp. 167-172. ISSN 0022-328X
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...
Related URL: http://dx.doi.org/10.1016/0022-328X(91)86204-4
Abstract
An improved method for isolation of pure Fe3(CO)9(μ3-Se)(μ3-Te) and Fe2(CO)6(μ-SeTe) has been developed. The mixed chalcogenide complex (CO)6Fe2(μ3-Se)(μ3-Te)Pt(PPh3)2 is formed exclusively on treatment of Fe2(CO)6(μ3-Se)(μ3-Te) with Pt(C2H4)(PPh3)2, or along with Fe3(PPh3)2(μ3-Se)(μ3-Te) when Fe3(CO)9(μ3-Se)(μ3-Te) is treated with Pt(PPh3)4. With PPh3, Fe3(CO)9(μ3-Se)(μ3-Te) forms an adduct, (CO)6Fe2(μ3-Se)(μ3-Te)Fe(CO)3(PPh3).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 24840 |
| Deposited On: | 01 Dec 2010 12:40 |
| Last Modified: | 01 Dec 2010 12:40 |
Repository Staff Only: item control page
