Facile synthesis of Ru4(CO)10(μ-CO)(μ4-Se)2 and its reactions with phosphine ligands

Mathur, Pradeep ; Munkir Hossain, Md. ; Rashid, Raad S. (1993) Facile synthesis of Ru4(CO)10(μ-CO)(μ4-Se)2 and its reactions with phosphine ligands Journal of Organometallic Chemistry, 448 (1-2). pp. 211-214. ISSN 0022-328X

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Official URL: http://dx.doi.org/10.1016/0022-328X(93)80086-Q

Related URL: http://dx.doi.org/10.1016/0022-328X(93)80086-Q

Abstract

The title compound has been prepared by refluxing a benzene solution containing Fe3(CO)93-Se)2 and Ru3(CO)12 or by stirring a benzene solution containing Ru3(CO)9(/gm3-Se)2 and Ru(CO)4(C2H4) at room temperature. Its reactions with triphenylphosphine, bis(diphenylphosphino)methane and bis(diphenylphosphino)ethane give tetraruthenium and triruthenium phosphine derivatives.

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