Synthesis and structural characterisation of a novel tris-methylene bridged compound (NO)4Fe2 Se(μ-CH2)3

Mathur, Pradeep ; Manimaran, Bala ; Munkir Hossain, Md. ; Rheingold, Arnold L. ; Liable-Sands, Louise M. ; Yap, Glenn P. A. (1997) Synthesis and structural characterisation of a novel tris-methylene bridged compound (NO)4Fe2 Se(μ-CH2)3 Journal of Organometallic Chemistry, 540 (1-2). pp. 165-168. ISSN 0022-328X

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...

Related URL: http://dx.doi.org/10.1016/S0022-328X(97)00134-4

Abstract

The tris-methylene bridged compound (NO)4Fe2Se(μ -CH2)3 has been isolated. It has been characterised by IR and 1H, 13C, and 77Se NMR spectroscopy. Its structure has been determined by single-crystal X-ray diffraction methods. The structure consists of a heavy atom triangle consisting of one Se and two Fe atoms. The Fe-Fe and the two Fe-Se edges are bridged by methylene groups.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Chalcogen; Alkylidene Clusters
ID Code:24834
Deposited On:30 Nov 2010 09:28
Last Modified:30 Nov 2010 09:28

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