Mixed chalcogen carbonyl compounds: III. Construction of the new unsaturated mixed metal clusters Fe2Ru2(CO)10(μ-CO)(μ4-Se)(μ4-Te) and Fe3Ru(CO)10(μ-CO)(μ4-Te)

Mathur, Pradeep ; Chakrabarty, Debojit ; Munkir Hossain, Md. (1991) Mixed chalcogen carbonyl compounds: III. Construction of the new unsaturated mixed metal clusters Fe2Ru2(CO)10(μ-CO)(μ4-Se)(μ4-Te) and Fe3Ru(CO)10(μ-CO)(μ4-Te) Journal of Organometallic Chemistry, 418 (3). pp. 415-420. ISSN 0022-328X

Full text not available from this repository.

Official URL: http://dx.doi.org/10.1016/0022-328X(91)80226-A

Related URL: http://dx.doi.org/10.1016/0022-328X(91)80226-A

Abstract

Addition of Ru(CO)4(C2H4)to Fe2Ru(CO)93-Se)(μ3-Te) and Fe3(CO)93-Se)(μ3-Te) lead to a clean formation of the new unsaturated mixed metal, mixed chalcogen carbonyl clusters, Fe2Ru2(CO)10(μ-CO)(μ4-Se)(μ4-Te) and Fe3Ru(CO)10(μ-CO)(μ4-Se)(μ4-Te) respectively. The Fe3Ru cluster is also obtainable from the photolysis of a solution containing Fe2Ru(CO)93-Se)(μ3-Te) and Fe(CO)5.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:24825
Deposited On:30 Nov 2010 09:20
Last Modified:30 Nov 2010 09:20

Repository Staff Only: item control page