Mathur, Pradeep ; Boodida, Sathyanarayana ; Ji, Radhe Shyam ; Mobin, Shaikh M. (2009) Fe(CO)5 promoted C-S bond activation and formation of an unusual C2S3 ligand in [{Fe2(CO)6}2(μ-C2S3)] Journal of Organometallic Chemistry, 694 (18). pp. 3043-3045. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2009.05.023
Abstract
Photolysis of a hexane solution containing Fe(CO)5 and CS2 leads to desulfurization and formation of a novel cluster [{Fe2(CO)6}2(μ-C2S3)] (1). Its molecular structure was determined by single crystal X-ray diffraction methods and shown to consist of two distinct Fe2(CO)6 units linked by an unusual C2S3 unit.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Iron Pentacarbonyl; Carbon Disulfide; C-S Bond Cleavage; Crystal Structure |
| ID Code: | 24824 |
| Deposited On: | 30 Nov 2010 09:19 |
| Last Modified: | 30 Nov 2010 09:19 |
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