Thakuria, Ranjit ; Sarma, Bipul ; Nangia, Ashwini (2008) Guest control in the self-assembly of H-shaped host to cyclopentanoid (5,43) net Crystal Growth & Design, 8 (5). pp. 1471-1473. ISSN 1528-7483
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Official URL: http://pubs.acs.org/doi/abs/10.1021/cg800089v
Related URL: http://dx.doi.org/10.1021/cg800089v
Abstract
The H-shaped molecule 1,4-di[bis(4'-hydroxyphenyl)methyl]benzene (1a) and its octamethyl derivative (1b) crystallize in solvated and guest-free forms. CH3NO2 and CHCl3 solvents afforded the rare (5,43) net of contiguous pentagons in a two-dimensional (2D) sheet for 1a and 1b, respectively. The tetrahedral carbon centers are 3-connected nodes and hydrogen bonding OH groups are 4-center nodes of congruent cyclopentanoid rings. The first examples of pentagon layer tiling in a lattice inclusion host are reported.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 24560 |
| Deposited On: | 29 Nov 2010 08:31 |
| Last Modified: | 04 Mar 2011 05:19 |
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