Flash photolysis study of the oxygenation of cobalt(II)-amine complexes: evidence for the formation of μ-superoxo dinuclear complex

Ramamurthy, P. ; Natarajan, P. (1985) Flash photolysis study of the oxygenation of cobalt(II)-amine complexes: evidence for the formation of μ-superoxo dinuclear complex Journal of the Chemical Society, Chemical Communications (22). pp. 1554-1555. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1985...

Related URL: http://dx.doi.org/10.1039/C39850001554

Abstract

cis-[Co(pn)2(NO2)2]+ ion (pn = 1,2-diaminopropane), after flash photolysis, reacts with dioxygen in two steps to form a μ-superoxo dinuclear cobalt(III) complex.

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