Anbalagan, K. ; Natarajan, P. (1991) Thermal and photoreactivities of oxalatobis(polypyridyl)chromium(III) complexes in aqueous media Proceedings of the Indian Academy of Sciences - Chemical Sciences, 103 (6). pp. 715-724. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/103/1/715-7...
Related URL: http://dx.doi.org/10.1007/BF02867324
Abstract
The thermal and photochemistry of oxalatobis(polypyridyl)chromium(III) complexes have been studied. The rate constants for the thermal aquation reactions have been determined and the quantum yield for the photoaquation has been estimated as a function of excitation wavelength and pH of the solution. The quantum yield for photoaquation varies from 7×10-2 to 10-3 depending upon the pH of the solution and wavelength of excitation. The activation parameters for the thermal reactions have been estimated for the systems investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Photochemistry; Chromium(III)-polypyridyl Complexes |
| ID Code: | 24416 |
| Deposited On: | 29 Nov 2010 08:58 |
| Last Modified: | 17 May 2016 08:07 |
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