Natarajan, P. ; Ferraudi, G. (1981) Photochemical properties of copper(II)-amino acid complexes Inorganic Chemistry, 20 (11). pp. 3708-3712. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic50225a025
Related URL: http://dx.doi.org/10.1021/ic50225a025
Abstract
The photochemistry of copper(II)-amino acid complexes (amino acid = glutamic acid, β-alanine, or glycine) has been investigated by continuous and flash photolysis. The charge-transfer irradiations induce the oxidation of the ligand and the reduction of copper(II) to copper(I). Transients observed in flash photolysis have been assigned as copper-alkyl complexes. Moreover, other copper-alkyl species are produced when carbon-centered radicals react with excess of copper(II) complexes. The photochemical properties of the copper(II)-amino acid complexes are discussed in terms of population of charge transfer to copper excited states.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 24352 |
| Deposited On: | 29 Nov 2010 09:06 |
| Last Modified: | 10 Jun 2011 06:02 |
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