35Cl powder zeeman NQR studies using an injection- and phase-locked NQR spectrometer

Harihara Subramanian, V. ; Narasimhan, P. T. (1980) 35Cl powder zeeman NQR studies using an injection- and phase-locked NQR spectrometer Journal of Molecular Structure, 58 . pp. 193-203. ISSN 0022-2860

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002228...

Related URL: http://dx.doi.org/10.1016/0022-2860(80)85021-6

Abstract

Results of 35Cl Zeeman NQR studies on powder samples of p-dichlo-robenzene (I) and mercuric chloride (II) conducted with a newly designed injection- and phase-locked NQR spectrometer with signal averaging capability are presented. The η value obtained by comparison with computer simulated spectra for both I and II is 0.08. It is shown -that the 'η-kinks' in the experimental powder Zeeman NQR spectra are extremely sensitive to modulation broadening and that one can be easily misled into identifying the strong deflections in the background signal as 'η-kinks' thus obtaining larger and incorrect η values. It is concluded that use of spectrometers with signal averaging capability is essential for obtaining reliable powder Zeeman NQR spectra.

Item Type:Article
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ID Code:24230
Deposited On:29 Nov 2010 09:24
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