Theoretical method of evaluation of heats of vaporisation of fused salts

Gopala Rao, R. ; Venkatesh, R. (1990) Theoretical method of evaluation of heats of vaporisation of fused salts Physica Status Solidi B, 157 (1). pp. 65-69. ISSN 0370-1972

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/pssb.22...

Related URL: http://dx.doi.org/10.1002/pssb.2221570104

Abstract

Starting with neutral hard spheres the entropy of vaporisation is calculated after mixing and charging them. The entropy contribution in overcoming the attraction is computed by the use of a potential function and the principle that the total entropy is a sum of the contributions from hard spheres and Coulomb interactions. The theoretical results are found to be in very good agreement with experiment except for lithium salts.

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