Chaudhuri, Mihir K. ; Islam, Nashreen S. (1985) Reactions of vanadium(V) with alkali sulphate or thiocyanate. Evidence for the formation of oxodiperoxovanadate(V) complexes containing ionic sulphate Transition Metal Chemistry, 10 (9). pp. 333-335. ISSN 0340-4285
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Official URL: http://www.springerlink.com/content/p6561207g2027n...
Related URL: http://dx.doi.org/10.1007/BF01036394
Abstract
Vanadium pentoxide (1 mol) reacts with alkali sulphate (2 mol) or alkali thiocyanate (2 mol) and an excess of hydrogen peroxide at pH 7-8, maintained by the addition of the corresponding alkali hydroxide, to produce yellow oxodiperoxovanadate(V) complexes containing sulphate. The compounds were characterised by elemental analyses, molar conductance measurements, and i.r. and laser Raman spectroscopic studies. The compounds are formulated as M[VO(O2)2] . M2SO4 (M=alkali metal). The peroxide has been shown to be bonded to the vanadium(V) centre in a triangular bidentate (C 2v) manner.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer Verlag. |
| ID Code: | 23558 |
| Deposited On: | 25 Nov 2010 13:08 |
| Last Modified: | 30 May 2011 08:37 |
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