Bhattacharjee, Chira R. ; Chaudhuri, Mihir K. ; Chettri, Shiv K. ; Laiwan, John J. (1994) Fluoroperoxouranates (VI). Synthesis and physico-chemical studies of (NH4)2[UO2(O2)F2] and K2[UO2(O2)F2(H2O)] Journal of Fluorine Chemistry, 66 (3). pp. 229-231. ISSN 0022-1139
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002211...
Related URL: http://dx.doi.org/10.1016/0022-1139(93)02923-3
Abstract
Complex peroxouranates (NH4)2[UO2(O2)F2] (1) and K2[UO2(O2)F2(H2O)] (2) have been synthesized from the reaction of UO3.4H2O with AHF2 (A = NH4 or K) and hydrogen peroxide. The reaction of 1 with SO2(g) in an aqueous medium afforded a fluoro(sulfato)dioxouranate(VI) complex (NH4)2[UO2F2(SO4)].H2O (3). Infrared and laser Raman spectroscopic studies have been made.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 23555 |
Deposited On: | 25 Nov 2010 13:09 |
Last Modified: | 30 May 2011 07:13 |
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