Bhattacharjee, Manabendra N. ; Chaudhuri, Mihir K. (1986) Ammonium and potassium fluoromonooxalatomanganates(II), A[MnF(C2O4)] (A = NH4 or K) and sodium fluoromonooxalatomanganate(II) dihydrate, Na[MnF(C2O4)]. 2H2O Transition Metal Chemistry, 11 (5). pp. 193-195. ISSN 0340-4285
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Official URL: http://www.springerlink.com/content/l71171w23534j4...
Related URL: http://dx.doi.org/10.1007/BF01064256
Abstract
Light pink-white microcrystalline ammonium and potassium fluoromonooxalatomanganates(II), A[MnF(C2O4)] (A = NH4 or K), and sodium fluoromonooxalatomanganate(II) dihydrate, Na[MnF(C2O4)] . 2H2O, have been synthesized by two different methods. Either KMnO4 is reduced in the presence of 40% HF and alkali metal oxalate, A2C2O4 (A = NH4, Na or K), or MnO(OH) in 40% HF reacts with A2C2O4. Characterisation was made by elemental analyses, determination of oxidation states, magnetic susceptibility measurements and infrared spectral studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer Verlag. |
| ID Code: | 23537 |
| Deposited On: | 25 Nov 2010 13:10 |
| Last Modified: | 30 May 2011 07:46 |
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