Chaudhuri, Mihir K. ; Roy, Nirmalendu (1982) Synthesis and spectroscopic studies of alkali pentafluoroaquochromates (III) Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 12 (7). pp. 879-887. ISSN 1553-3174
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Related URL: http://dx.doi.org/10.1080/00945718208056023
Abstract
Chromium(VI) oxide undergoes a very facile reduction with formaldehyde solution in the presence of 40% hydrofluoric acid and AF (A = NH4+, Na+, K+ or Rb+) giving green, crystalline A2[CrF5(H2O)-] in very high yields. The structural assessment of the compounds was made from magnetic moments, infrared and electronic spectroscopic data. The electronic spectra of A2[CrF5(H2O)-] in the solid state and in solution suggest no apparent change in its structure.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Group. |
| ID Code: | 23527 |
| Deposited On: | 25 Nov 2010 13:11 |
| Last Modified: | 30 May 2011 08:50 |
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