Synthesis and spectroscopic studies of alkali pentafluoroaquochromates (III)

Chaudhuri, Mihir K. ; Roy, Nirmalendu (1982) Synthesis and spectroscopic studies of alkali pentafluoroaquochromates (III) Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 12 (7). pp. 879-887. ISSN 1553-3174

Full text not available from this repository.

Official URL: http://www.informaworld.com/smpp/content~db=all~co...

Related URL: http://dx.doi.org/10.1080/00945718208056023

Abstract

Chromium(VI) oxide undergoes a very facile reduction with formaldehyde solution in the presence of 40% hydrofluoric acid and AF (A = NH4+, Na+, K+ or Rb+) giving green, crystalline A2[CrF5(H2O)-] in very high yields. The structural assessment of the compounds was made from magnetic moments, infrared and electronic spectroscopic data. The electronic spectra of A2[CrF5(H2O)-] in the solid state and in solution suggest no apparent change in its structure.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Group.
ID Code:23527
Deposited On:25 Nov 2010 13:11
Last Modified:30 May 2011 08:50

Repository Staff Only: item control page