Mechanism of formation of formaldehyde in the flash photolysis of methyl formate

Krishnamachari, S. L. N. G. (1974) Mechanism of formation of formaldehyde in the flash photolysis of methyl formate Photochemistry and Photobiology, 20 (1). pp. 33-35. ISSN 0031-8655

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Official URL: http://onlinelibrary.wiley.com/doi/10.1111/j.1751-...

Related URL: http://dx.doi.org/10.1111/j.1751-1097.1974.tb06544.x

Abstract

From flash photolyses of methyl formate (HCOOCH3), d-methyl formate (DCOOCH3), methyl formate-d3 (HCOOCD3) and fully *** deuterated methyl formate (DCOOCD3) in the vapour phase at room temperature, the relative efficiencies of the formyl and methoxyl radicals in producing formaldehyde have been determined.

Item Type:Article
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