Structure of high-Tc superconducting Bi-Sr-Ca-Cu-O films prepared by spray pyrolysis

Roul, B. K. ; Pramanik, P. ; Chopra, K. L. (1989) Structure of high-Tc superconducting Bi-Sr-Ca-Cu-O films prepared by spray pyrolysis Physica C: Superconductivity and its Applications, 160 (5-6). pp. 439-442. ISSN 0921-4534

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/092145...

Related URL: http://dx.doi.org/10.1016/0921-4534(89)90417-6

Abstract

High-Tc superconducting films of Bi-Sr-Ca-Cu-O have been synthesized by spray pyrolysis of nitrate precursors onto yttria stabilized zirconia (YSZ), followed by rapid annealing at 840°C in air/oxygen. The films are preferentially oriented with c-axis parallel to the plane of the substrate surface. The diffraction patterns of the films correspond to a mixed phase orthorhombic structure, with different c-values of 24.49 Å, 30.78 Å and 37.25 Å. These films exhibit superconductivity at 91 K and zero resistance at 77 K.

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