Prasad, S. D. ; Doraiswamy, L. K. (1984) Exact solution of the adsorption integral equation for a heterogeneous surface Chemical Physics Letters, 108 (1). pp. 83-86. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(84)80372-3
Abstract
An exact method of solution of the adsorption integral equation using finite and realistic limits of the heats of adsorption and which is applicable to any analytic site-energy distribution is given. The optical feature is the postulation and use of a set of transformations to reduce the finite-limit problem to one of limits (0, ∞). The transformed integral equation is then inverted using the theory of Stieltjes transforms. The method thus avoids the limitations inherent in earlier work which employed restrictive assumptions about the heats of adsorption.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 22810 |
| Deposited On: | 24 Nov 2010 08:29 |
| Last Modified: | 31 May 2011 06:07 |
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