Adhikary, Bibhutosh ; Nanda, Kausik K. ; Das, Ramprasad ; Mandal, Sanat K. ; Nag, Kamalaksha (1992) Synthesis, characterization and electrochemistry of copper(II), nickel(II), cobalt(II) and zinc(II) complexes of a binucleating ligand with [N2S]2O donors Polyhedron, 11 (3). pp. 347-353. ISSN 0277-5387
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S02775...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)83180-0
Abstract
A heptadentate ligand (H3L) with a phenoxo group bridging two metal centres has been synthesized by reacting 4-methyl-2,6-diformylphenol with methyl 2-((2-aminoethyl)amino)cyclopent-l-enedithiocarboxylate. Mono- and binuclear complexes of copper(II), nickel(II), cobalt(II) and zinc(II) have been synthesized and characterized by their UV-vis, IR, 1H and 13C NMR and EPR spectra. The electrochemistry of the complexes has been studied and the factors affecting electron-transfer reactions of the binuclear complexes vis-á-vis corresponding mononuclear complexes have been examined.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 22669 |
| Deposited On: | 24 Nov 2010 08:03 |
| Last Modified: | 23 Jan 2011 16:08 |
Repository Staff Only: item control page
