Balaraman, K. S. ; Nadkarni, V. M. ; Mashelkar, R. A. (1986) San bulk copolymerization: some new insights in kinetics and microstructure Chemical Engineering Science, 41 (5). pp. 1357-1368. ISSN 0009-2509
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000925...
Related URL: http://dx.doi.org/10.1016/0009-2509(86)87109-3
Abstract
A comprehensive study of the kinetics of the industrially important system of free radical bulk copolymerization of styrene and acrylonitrile, both at low and high conversions, is presented. The influence of gel effect on the kinetics, molecular weight distribution, cumulative composition distribution and the sequence length distribution of the SAN copolymer is examined. The study provides a fresh insight into the polymer structure and the influence of gel effect on the reactor behaviour.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 22244 |
| Deposited On: | 23 Nov 2010 08:30 |
| Last Modified: | 13 Jul 2012 10:22 |
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