Kulkarni, M. G. ; Mashelkar, R. A. (1981) Diffusion effects in initiator decomposition in highly viscous and macromolecular solutions AIChE Journal, 27 (5). pp. 716-724. ISSN 0001-1541
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/aic.690...
Related URL: http://dx.doi.org/10.1002/aic.690270503
Abstract
Diffusional limitations in single bond and multibond initiators were experimentally investigated. The concept of "microviscosity" was proposed to account for diffusional resistance in different media. This was then used to obtain a unified correlation of the diffusional phenomena regardless of the nature of viscogen. Parameters related to the kinetic and diffusive processes were evaluated and interpreted giving clear fundamental and pragmatic implications of the findings.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Chemical Engineers. |
| ID Code: | 22241 |
| Deposited On: | 23 Nov 2010 08:29 |
| Last Modified: | 17 Jul 2012 00:43 |
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