Basu, Amitabha ; Bhaduri, Sumit ; Khwaja, Hanif ; Jones, Peter G. ; Meyer-Base, Karen ; Sheldrick, George M. (1986) Reaction of nitrobenzene with [M3(CO)12](M = Fe or Ru) in the presence of [Co2(CO)8]: isolation and structure of [Ru3(CO)7(NPh)(η6-C6H6)] Journal of the Chemical Society Dalton Transactions . pp. 2501-2503. ISSN 1472-7773
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Official URL: http://www.rsc.org/publishing/journals/DT/article....
Related URL: http://dx.doi.org/10.1039/DT9860002501
Abstract
The complexes [Ru3(CO)7(NPh)(C6H6)](1) and [FeCo2(CO)9(NPh)](2) are formed in the reactions between PhNO2 and [M3(CO)12](M = Ru or Fe) only when [Co2(CO)8] is present. The structure of (1) has been determined by X-ray diffraction; it contains triply bridging CO and PhN ligands and an η6-benzene ligand co-ordinated to only one metal atom.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 2159 |
| Deposited On: | 08 Oct 2010 09:02 |
| Last Modified: | 18 Jan 2011 05:00 |
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