Use of isotopes for studying reaction mechanisms. 4. Distinguishing between single minima and rapidly equilibrating structures

Maitra, Uday ; Chandrasekhar, J. (1997) Use of isotopes for studying reaction mechanisms. 4. Distinguishing between single minima and rapidly equilibrating structures Resonance - Journal of Science Education, 2 (10). pp. 29-37. ISSN 0971-8044

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Abstract

The method of isotopic perturbation of equilibrium is described. In conjunction with nuclear magnetic resonance spectroscopy, the procedure can be used to distinguish between double well and single minimum potential energy surfaces. Some representative studies on classical and non-classical carbocations are discussed.

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Deposited On:20 Nov 2010 13:07
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