Conversion of the cholesterol sidechain to a 17-acetyl group by remote chlorination reactions

Maitra, Uday ; Breslow, Ronald (1986) Conversion of the cholesterol sidechain to a 17-acetyl group by remote chlorination reactions Tetrahedron Letters, 27 (27). pp. 3087-3090. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)84722-X

Abstract

Two methods to convert cholesterol to pregnane derivatives are described. In one, template directed chlorination of C-20 with an iodoaryl ester attached at the 6 β position was used to convert i-cholesterol to pregnenolone.

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