Ruthenium-cluster-catalysed transfer hydrogenation of carbon tetrahalides: isolation and X-ray structure of an active intermediate, Ru3(CO)7Cl2(OC6H11)2

Bhaduri, Sumit ; Sapre, Niteen Y. ; Sharma, Krishna R. ; Jones, Peter G. (1989) Ruthenium-cluster-catalysed transfer hydrogenation of carbon tetrahalides: isolation and X-ray structure of an active intermediate, Ru3(CO)7Cl2(OC6H11)2 Journal of Organometallic Chemistry, 364 (1-2). C8-C10. ISSN 0022-328X

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...

Related URL: http://dx.doi.org/10.1016/0022-328X(89)85354-9 |

Abstract

Trinuclear and tetranuclear ruthenium clusters act as active intermediates in the transfer hydrogenation reactions of CX4 (X = Cl, Br); a representative trinuclear species Ru3(CO)7Cl2(OC6H11)2 has been characterised.

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ID Code:2094
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